A new pH phenomenon to predict polarity reversal in lead-acid cells

Mooney, J. and Alaswad, A. and Cruden, A. (2016) A new pH phenomenon to predict polarity reversal in lead-acid cells. Energy, 136. pp. 100-109. ISSN 0360-5442

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Abstract

This paper discusses new experimental work investigating the change in pH of the electrolyte of individual cells in Lead-Acid batteries during discharge with a view to predicting cell polarity reversal and thereby pre-empting potentially catastrophic failure in batteries. The discharge tests were carried out on batteries which were classified as ‘new’ and ‘aged’ as a means of indicating their state of health. A new pH phenomenon has been recorded for the first time in this paper as evidenced by experimental results
including measurement of half-cell potentials. The trends observed during the discharge tests could be used as additional means of indicating impending cell reversal in series connected lead-acid cells.

Item Type: Article
Identification Number: https://doi.org/10.1016/j.energy.2016.04.083
Dates:
DateEvent
30 May 2016Published Online
15 April 2016Accepted
Subjects: CAH26 - geography, earth and environmental studies > CAH26-01 - geography, earth and environmental studies > CAH26-01-02 - physical geographical sciences
Divisions: Faculty of Computing, Engineering and the Built Environment
Faculty of Computing, Engineering and the Built Environment > School of Engineering and the Built Environment
Faculty of Computing, Engineering and the Built Environment > School of Engineering and the Built Environment > School of Engineering
Depositing User: Ian Mcdonald
Date Deposited: 14 Dec 2016 15:30
Last Modified: 22 Mar 2023 12:11
URI: https://www.open-access.bcu.ac.uk/id/eprint/3691

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